[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '3\tsigma\t4\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-H [H:21][C@@:20](C)(CC)C#N.[NH2-:10]>>[H-:21].CC[C@:20](C)(C#N)[NH2:10] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '9\tsigma\t1\t2; 3\tsigma\t4\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:20][CH2:21][C@:22]([H:23])(CC)C#N.[NH2-:10]>>[H-:23].[H:20][NH2:10].CC[C@@:22](=[CH2:21])C#N 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '12\tsigma\t2\t2; 3\tsigma\t4\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:20][CH:21](C)[C@@:22]([H:23])(C)C#N.[NH2-:10]>>[H-:23].[H:20][NH2:10].C[CH:21]=[C@@:22](C)C#N 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '8\tpi\t7\t2; 3\tsigma\t4\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > π^*_N#C > σ^*_C-H [H:23][C@@:22](C)(CC)[C:21]#[N:20].[NH2-:10]>>[H-:23].CC[C@:22](=[C:21]=[N:20][NH2:10])C 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '3\tsigma\t1\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-C CC[C@@H:20]([CH3:21])C#N.[NH2-:10]>>[CH3-:21].CC[C@@H:20](C#N)[NH2:10] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '12\tsigma\t2\t2; 3\tsigma\t1\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][CH:21](C)[C@@H:22]([CH3:23])C#N.[NH2-:10]>>[H:20][NH2:10].[CH3-:23].C[CH:21]=[C@@H:22]C#N 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '8\tpi\t7\t2; 3\tsigma\t1\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > π^*_N#C > σ^*_C-C CC[C@@H:22]([CH3:23])[C:21]#[N:20].[NH2-:10]>>[CH3-:23].CC[C@@H:22]=[C:21]=[N:20][NH2:10] 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '3\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-C C[CH2:21][C@@H:20](C)C#N.[NH2-:10]>>C[CH2-:21].C[C@H:20](C#N)[NH2:10] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '9\tsigma\t1\t2; 3\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][CH2:21][C@H:22]([CH2:23]C)C#N.[NH2-:10]>>[H:20][NH2:10].C[CH2-:23].[CH2:21]=[C@@H:22]C#N 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '8\tpi\t7\t2; 3\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > π^*_N#C > σ^*_C-C C[CH2:23][C@@H:22](C)[C:21]#[N:20].[NH2-:10]>>C[CH2-:23].C[C@H:22]=[C:21]=[N:20][NH2:10] 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '3\tsigma\t7\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-C CC[C@@H:20](C)[C:21]#N.[NH2-:10]>>CC[C@H:20](C)[NH2:10].[C-:21]#N 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '9\tsigma\t1\t2; 3\tsigma\t7\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][CH2:21][C@H:22](CC)[C:23]#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H:22]=[CH2:21].[C-:23]#N 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '12\tsigma\t2\t2; 3\tsigma\t7\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][CH:21](C)[C@@H:22](C)[C:23]#N.[NH2-:10]>>[H:20][NH2:10].C[CH:21]=[C@@H:22]C.[C-:23]#N 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '1\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-C CC[C@@H:21]([CH3:20])C#N.[NH2-:10]>>CC[C@@H-:21]C#N.[CH3:20][NH2:10] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '1\tsigma\t9\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-H [H:21][CH2:20][C@H](CC)C#N.[NH2-:10]>>[H-:21].CC[C@@H]([CH2:20][NH2:10])C#N 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '2\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-C C[CH2:20][C@@H:21](C)C#N.[NH2-:10]>>C[CH2:20][NH2:10].C[C@H-:21]C#N 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '14\tsigma\t6\t2; 2\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][CH2:21][CH2:22][C@@H:23](C)C#N.[NH2-:10]>>[H:20][NH2:10].C[C@H-:23]C#N.[CH2:21]=[CH2:22] 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '2\tsigma\t6\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-C [CH3:21][CH2:20][C@@H](C)C#N.[NH2-:10]>>[CH3-:21].C[C@H]([CH2:20][NH2:10])C#N 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '4\tsigma\t3\t2; 2\tsigma\t6\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][C@@:21](C)([CH2:22][CH3:23])C#N.[NH2-:10]>>[H:20][NH2:10].[CH3-:23].C[C@:21](=[CH2:22])C#N 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '2\tsigma\t12\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-H [H:21][CH:20](C)[C@@H](C)C#N.[NH2-:10]>>[H-:21].C[C@@H](C#N)[CH:20](C)[NH2:10] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '14\tsigma\t6\t2; 2\tsigma\t12\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:20][CH2:21][CH:22]([H:23])[C@@H](C)C#N.[NH2-:10]>>[H-:23].[H:20][NH2:10].C[C@H]([CH:22]=[CH2:21])C#N 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '6\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-C [CH3:20][CH2:21][C@@H](C)C#N.[NH2-:10]>>C[C@H]([CH2-:21])C#N.[CH3:20][NH2:10] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '6\tsigma\t14\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-H [H:21][CH2:20]C[C@@H](C)C#N.[NH2-:10]>>[H-:21].C[C@H](C[CH2:20][NH2:10])C#N 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '7\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_C-C CC[C@@H:21](C)[C:20]#N.[NH2-:10]>>CC[C@@H-:21]C.[C:20](#N)[NH2:10] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '7\tpi\t8\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > π^*_C#N CC[C@@H](C)[C:20]#[N:21].[NH2-:10]>>CC[C@@H](C)[C:20](=[N-:21])[NH2:10] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '4\tsigma\t3\t2; 7\tpi\t8\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C > π^*_C#N [H:20][C@@:21](C)(CC)[C:22]#[N:23].[NH2-:10]>>[H:20][NH2:10].CC[C@:21](=[C:22]=[N-:23])C 10=20;20,21=21,22;22,23=23
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '8\tpi\t7\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > π^*_N#C CC[C@@H](C)[C:21]#[N:20].[NH2-:10]>>CC[C@@H](C)[C-:21]=[N:20][NH2:10] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '9\tsigma\t1\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C [H:20][CH2:21][C@H](CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H]([CH2-:21])C#N 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '12\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C [H:20][CH:21](C)[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].C[CH-:21][C@@H](C)C#N 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '14\tsigma\t6\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C [H:20][CH2:21]C[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].C[C@H](C[CH2-:21])C#N 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('1\tsigma\t9\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-H > σ^*_H-C [H:11][CH2:10][C@:21]([H:20])(CC)C#N.[NH2-]>>[H+:11].[H:20][CH2:10][C@-:21](CC)C#N.[NH2-] 10,11=10,20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('2\tsigma\t6\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-C > σ^*_H-C [H:20][C@@:21](C)([CH2:10][CH3:11])C#N.[NH2-]>>[H:20][CH2:10][C@@-:21](C)C#N.[CH3+:11].[NH2-] 10,11=10,20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('6\tsigma\t2\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-C > σ^*_H-C [H:20][C@@:21](C)([CH2:11][CH3:10])C#N.[NH2-]>>[H:20][CH3:10].C[C@-:21]([CH2+:11])C#N.[NH2-] 10,11=10,20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('7\tpi\t8\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
π_C#N > σ^*_H-C [H:20][C@@:21](C)(CC)[C:10]#[N:11].[NH2-]>>[H:20][C:10](=[N+:11])[C@-:21](C)CC.[NH2-] 10,11=10,20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('8\tpi\t7\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
π_N#C > σ^*_H-C [H:20][C@@:21](C)(CC)[C:11]#[N:10].[NH2-]>>[H:20][N:10]=[C+:11][C@-:21](C)CC.[NH2-] 10,11=10,20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('8\tsp\tNone\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#[N:10].[NH2-]>>[H:20][N+:10]#C[C@-:21](C)CC.[NH2-] 10=20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('9\tsigma\t1\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
σ_H-C > σ^*_H-C [H:10][CH2:11][C@:21]([H:20])(CC)C#N.[NH2-]>>[H:20][H:10].CC[C@@-:21]([CH2+:11])C#N.[NH2-] 10,11=10,20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('12\tsigma\t2\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
σ_H-C > σ^*_H-C [H:10][CH:11](C)[C@@:21]([H:20])(C)C#N.[NH2-]>>[H:10][H:20].C[CH+:11][C@@-:21](C)C#N.[NH2-] 10,11=10,20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('14\tsigma\t6\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
σ_H-C > σ^*_H-C [H:10][CH2:11]C[C@@:21]([H:20])(C)C#N.[NH2-]>>[H:10][H:20].C[C@-:21](C[CH2+:11])C#N.[NH2-] 10,11=10,20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('17\tsigma\t5\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N 10=20;20,21=21
σ_H-N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[H:10][NH-:11]>>[H:20][H:10].CC[C@@-:21](C)C#N.[NH:11] 10,11=10,20;20,21=21
1

---

[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:10017][N-:10005][H:10018].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '10005\tsigma\t10017\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.[NH2-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)C#N.[NH2-] 10=20;20,21=21
n_N > σ^*_N-H [H:21][NH-:20].CC[C@@H](C)C#N.[NH2-:10]>>[H-:21].CC[C@@H](C)C#N.[NH2:10][NH-:20] 10=20;20,21=21
2

---

[H:10014][C:10006]([H:10015])([H:10016])[C:10002]([H:10012])([H:10013])[C@:10003]([H:10004])([C:10007]#[N:10008])[C:10001]([H:10009])([H:10010])[H:10011].[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10003\tsigma\t10002\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)C#N.CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-C > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.C[CH2:11][C@@H:10](C)C#N.[NH2-]>>[H][C@@:10]([H:20])(C)C#N.C[CH2+:11].CC[C@@-:21](C)C#N.[NH2-] 10,11=10,20;20,21=21
3

---

[H:10014][C:10006]([H:10015])([H:10016])[C:10002]([H:10012])([H:10013])[C@:10003]([H:10004])([C:10007]#[N:10008])[C:10001]([H:10009])([H:10010])[H:10011].[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10008\tpi\t10007\t2; 10003\tsigma\t10002\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)C#N.CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-C > π_N#C > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.C[CH2:13][C@@H:12](C)[C:11]#[N:10].[NH2-]>>[H:20][N:10]=[C:11]=[C@@H:12]C.C[CH2+:13].CC[C@@-:21](C)C#N.[NH2-] 10,11=10,20;12,13=11,12;20,21=21
3

---

[H:10014][C:10006]([H:10015])([H:10016])[C:10002]([H:10012])([H:10013])[C@:10003]([H:10004])([C:10007]#[N:10008])[C:10001]([H:10009])([H:10010])[H:10011].[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10003\tsigma\t10004\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)C#N.CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-H > σ^*_H-C [H:11][C@@:10](C)(CC)C#N.[H:20][C@@:21](C)(CC)C#N.[NH2-]>>[H+:11].[H:20][C@@:10](C)(CC)C#N.CC[C@@-:21](C)C#N.[NH2-] 10,11=10,20;20,21=21
3

---

[H:10014][C:10006]([H:10015])([H:10016])[C:10002]([H:10012])([H:10013])[C@:10003]([H:10004])([C:10007]#[N:10008])[C:10001]([H:10009])([H:10010])[H:10011].[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10008\tpi\t10007\t2; 10003\tsigma\t10004\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)C#N.CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-H > π_N#C > σ^*_H-C [H:13][C@@:12](C)(CC)[C:11]#[N:10].[H:20][C@@:21](C)(CC)C#N.[NH2-]>>[H+:13].[H:20][N:10]=[C:11]=[C@:12](C)CC.CC[C@@-:21](C)C#N.[NH2-] 10,11=10,20;12,13=11,12;20,21=21
3

---

[H:10014][C:10006]([H:10015])([H:10016])[C:10002]([H:10012])([H:10013])[C@:10003]([H:10004])([C:10007]#[N:10008])[C:10001]([H:10009])([H:10010])[H:10011].[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10003\tsigma\t10007\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)C#N.CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-C > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H:10](C)[C:11]#N.[NH2-]>>[H][C@@:10]([H:20])(C)CC.CC[C@@-:21](C)C#N.[C+:11]#N.[NH2-] 10,11=10,20;20,21=21
3

---

[H:10014][C:10006]([H:10015])([H:10016])[C:10002]([H:10012])([H:10013])[C@:10003]([H:10004])([C:10007]#[N:10008])[C:10001]([H:10009])([H:10010])[H:10011].[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10003\tsigma\t10001\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)C#N.CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-C > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H:10]([CH3:11])C#N.[NH2-]>>[H][C@:10]([H:20])(CC)C#N.[CH3+:11].CC[C@@-:21](C)C#N.[NH2-] 10,11=10,20;20,21=21
3

---

[H:10014][C:10006]([H:10015])([H:10016])[C:10002]([H:10012])([H:10013])[C@:10003]([H:10004])([C:10007]#[N:10008])[C:10001]([H:10009])([H:10010])[H:10011].[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10008\tpi\t10007\t2; 10003\tsigma\t10001\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)C#N.CC[C@@-:21](C)C#N 10=20;20,21=21
σ_C-C > π_N#C > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H:12]([CH3:13])[C:11]#[N:10].[NH2-]>>[H:20][N:10]=[C:11]=[C@H:12]CC.[CH3+:13].CC[C@@-:21](C)C#N.[NH2-] 10,11=10,20;12,13=11,12;20,21=21
3

---

[H:10014][C:10006]([H:10015])([H:10016])[C:10002]([H:10012])([H:10013])[C@:10003]([H:10004])([C:10007]#[N:10008])[C:10001]([H:10009])([H:10010])[H:10011].[H:14][C:6]([H:15])([H:16])[C:2]([H:12])([H:13])[C@:3]([H:4])([C:7]#[N:8])[C:1]([H:9])([H:10])[H:11].[H:17][N-:5][H:18]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10004\tsigma\t10003\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)C#N.CC[C@@H](C)C#N.[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)C#N.CC[C@@-:21](C)C#N 10=20;20,21=21
σ_H-C > σ^*_H-C [H:10][C@@:11](C)(CC)C#N.[H:20][C@@:21](C)(CC)C#N.[NH2-]>>[H:10][H:20].CC[C@@-:21](C)C#N.CC[C@@+:11](C)C#N.[NH2-] 10,11=10,20;20,21=21
3

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '3\tsigma\t4\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-H [H:21][C@@:20](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H-:21].CC[C@@:20](C)([NH2:10])[N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '10\tsigma\t1\t2; 3\tsigma\t4\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:20][CH2:21][C@:22]([H:23])(CC)[N+](=O)[O-].[NH2-:10]>>[H-:23].[H:20][NH2:10].CC[C@@:22](=[CH2:21])[N+](=O)[O-] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '13\tsigma\t2\t2; 3\tsigma\t4\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:20][CH:21](C)[C@@:22]([H:23])(C)[N+](=O)[O-].[NH2-:10]>>[H-:23].[H:20][NH2:10].C[CH:21]=[C@@:22](C)[N+](=O)[O-] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '8\tpi\t7\t2; 3\tsigma\t4\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > π^*_O=N > σ^*_C-H [H:23][C@@:22](C)(CC)[N+:21](=[O:20])[O-].[NH2-:10]>>[H-:23].CC[C@:22](=[N+:21]([O-])[O:20][NH2:10])C 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '3\tsigma\t1\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-C CC[C@@H:20]([CH3:21])[N+](=O)[O-].[NH2-:10]>>[CH3-:21].CC[C@H:20]([NH2:10])[N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '13\tsigma\t2\t2; 3\tsigma\t1\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][CH:21](C)[C@@H:22]([CH3:23])[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].[CH3-:23].C[CH:21]=[C@H:22][N+](=O)[O-] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '8\tpi\t7\t2; 3\tsigma\t1\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > π^*_O=N > σ^*_C-C CC[C@@H:22]([CH3:23])[N+:21](=[O:20])[O-].[NH2-:10]>>[CH3-:23].CC[C@H:22]=[N+:21]([O-])[O:20][NH2:10] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '3\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-C C[CH2:21][C@@H:20](C)[N+](=O)[O-].[NH2-:10]>>C[CH2-:21].C[C@@H:20]([NH2:10])[N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '10\tsigma\t1\t2; 3\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][CH2:21][C@H:22]([CH2:23]C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].C[CH2-:23].[CH2:21]=[C@H:22][N+](=O)[O-] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '8\tpi\t7\t2; 3\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > π^*_O=N > σ^*_C-C C[CH2:23][C@@H:22](C)[N+:21](=[O:20])[O-].[NH2-:10]>>C[CH2-:23].C[C@@H:22]=[N+:21]([O-])[O:20][NH2:10] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '3\tsigma\t7\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-N CC[C@@H:20](C)[N+:21](=O)[O-].[NH2-:10]>>CC[C@H:20](C)[NH2:10].[N:21](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '10\tsigma\t1\t2; 3\tsigma\t7\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-N [H:20][CH2:21][C@H:22](CC)[N+:23](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@H:22]=[CH2:21].[N:23](=O)[O-] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '13\tsigma\t2\t2; 3\tsigma\t7\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-N [H:20][CH:21](C)[C@@H:22](C)[N+:23](=O)[O-].[NH2-:10]>>[H:20][NH2:10].C[CH:21]=[C@H:22]C.[N:23](=O)[O-] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '1\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-C CC[C@@H:21]([CH3:20])[N+](=O)[O-].[NH2-:10]>>CC[C@H-:21][N+](=O)[O-].[CH3:20][NH2:10] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '1\tsigma\t10\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-H [H:21][CH2:20][C@H](CC)[N+](=O)[O-].[NH2-:10]>>[H-:21].CC[C@@H]([CH2:20][NH2:10])[N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '2\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-C C[CH2:20][C@@H:21](C)[N+](=O)[O-].[NH2-:10]>>C[CH2:20][NH2:10].C[C@H-:21][N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '15\tsigma\t6\t2; 2\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][CH2:21][CH2:22][C@@H:23](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].C[C@H-:23][N+](=O)[O-].[CH2:21]=[CH2:22] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '2\tsigma\t6\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-C [CH3:21][CH2:20][C@@H](C)[N+](=O)[O-].[NH2-:10]>>[CH3-:21].C[C@H]([CH2:20][NH2:10])[N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '4\tsigma\t3\t2; 2\tsigma\t6\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][C@@:21](C)([CH2:22][CH3:23])[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].[CH3-:23].C[C@:21](=[CH2:22])[N+](=O)[O-] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '2\tsigma\t13\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-H [H:21][CH:20](C)[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H-:21].C[CH:20]([C@@H](C)[N+](=O)[O-])[NH2:10] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '15\tsigma\t6\t2; 2\tsigma\t13\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:20][CH2:21][CH:22]([H:23])[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H-:23].[H:20][NH2:10].C[C@H]([CH:22]=[CH2:21])[N+](=O)[O-] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '6\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-C [CH3:20][CH2:21][C@@H](C)[N+](=O)[O-].[NH2-:10]>>C[C@H]([CH2-:21])[N+](=O)[O-].[CH3:20][NH2:10] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '6\tsigma\t15\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_C-H [H:21][CH2:20]C[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H-:21].C[C@H](C[CH2:20][NH2:10])[N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '7\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_N-C CC[C@@H:21](C)[N+:20](=O)[O-].[NH2-:10]>>CC[C@H-:21]C.[NH2:10][N+:20](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '7\tpi\t8\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > π^*_N=O CC[C@@H](C)[N+:20](=[O:21])[O-].[NH2-:10]>>CC[C@@H](C)[N+:20]([NH2:10])([O-:21])[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '4\tsigma\t3\t2; 7\tpi\t8\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > π^*_N=O [H:20][C@@:21](C)(CC)[N+:22](=[O:23])[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@:21](=[N+:22]([O-:23])[O-])C 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '7\tsigma\t9\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_N-O CC[C@@H](C)[N+:20](=O)[O-:21].[NH2-:10]>>CC[C@@H](C)[N+:20](=O)[NH2:10].[O-2:21] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '4\tsigma\t3\t2; 7\tsigma\t9\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_N-O [H:20][C@@:21](C)(CC)[N+:22](=O)[O-:23].[NH2-:10]>>[H:20][NH2:10].CC[C@:21](=[N+:22]=O)C.[O-2:23] 10=20;20,21=21,22;22,23=23
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '8\tpi\t7\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > π^*_O=N CC[C@@H](C)[N+:21](=[O:20])[O-].[NH2-:10]>>CC[C@@H](C)[N:21]([O-])[O:20][NH2:10] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '9\tsigma\t7\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_O-N CC[C@@H](C)[N+:21](=O)[O-:20].[NH2-:10]>>CC[C@@H](C)[N:21]=O.[NH2:10][O-:20] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '10\tsigma\t1\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C [H:20][CH2:21][C@H](CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@H]([CH2-:21])[N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '13\tsigma\t2\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C [H:20][CH:21](C)[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].C[CH-:21][C@@H](C)[N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '15\tsigma\t6\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_N > σ^*_H-C [H:20][CH2:21]C[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].C[C@H](C[CH2-:21])[N+](=O)[O-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('1\tsigma\t10\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-H > σ^*_H-C [H:11][CH2:10][C@:21]([H:20])(CC)[N+](=O)[O-].[NH2-]>>[H+:11].[H:20][CH2:10][C@-:21](CC)[N+](=O)[O-].[NH2-] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('2\tsigma\t6\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-C > σ^*_H-C [H:20][C@@:21](C)([CH2:10][CH3:11])[N+](=O)[O-].[NH2-]>>[H:20][CH2:10][C@@-:21](C)[N+](=O)[O-].[CH3+:11].[NH2-] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('6\tsigma\t2\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-C > σ^*_H-C [H:20][C@@:21](C)([CH2:11][CH3:10])[N+](=O)[O-].[NH2-]>>[H:20][CH3:10].C[C@-:21]([CH2+:11])[N+](=O)[O-].[NH2-] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('7\tpi\t8\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
π_N=O > σ^*_H-C [H:20][C@@:21](C)(CC)[N+:10](=[O:11])[O-].[NH2-]>>[H:20][N+:10]([C@-:21](C)CC)([O-])[O+:11].[NH2-] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('7\tsigma\t9\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_N-O > σ^*_H-C [H:20][C@@:21](C)(CC)[N+:10](=O)[O-:11].[NH2-]>>[H:20][N+:10](=O)[C@-:21](C)CC.[NH2-].[O:11] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('8\tpi\t7\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
π_O=N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+:11](=[O:10])[O-].[NH2-]>>[H:20][O:10][N+2:11]([C@-:21](C)CC)[O-].[NH2-] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('8\tsp2\tNone\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_O > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=[O:10])[O-].[NH2-]>>[H:20][O+:10]=[N+]([C@-:21](C)CC)[O-].[NH2-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('9\tsigma\t7\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_O-N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+:11](=O)[O-:10].[NH2-]>>[H:20][O-:10].CC[C@@-:21](C)[N+2:11]=O.[NH2-] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('9\tsp3\tNone\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
n_O > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-:10].[NH2-]>>[H:20][O:10][N+](=O)[C@-:21](C)CC.[NH2-] 10=20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10\tsigma\t1\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_H-C > σ^*_H-C [H:10][CH2:11][C@:21]([H:20])(CC)[N+](=O)[O-].[NH2-]>>[H:20][H:10].CC[C@@-:21]([CH2+:11])[N+](=O)[O-].[NH2-] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('13\tsigma\t2\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_H-C > σ^*_H-C [H:10][CH:11](C)[C@@:21]([H:20])(C)[N+](=O)[O-].[NH2-]>>[H:10][H:20].C[CH+:11][C@@-:21](C)[N+](=O)[O-].[NH2-] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('15\tsigma\t6\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_H-C > σ^*_H-C [H:10][CH2:11]C[C@@:21]([H:20])(C)[N+](=O)[O-].[NH2-]>>[H:10][H:20].C[C@-:21](C[CH2+:11])[N+](=O)[O-].[NH2-] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('18\tsigma\t5\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_H-N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[H:10][NH-:11]>>[H:20][H:10].CC[C@@-:21](C)[N+](=O)[O-].[NH:11] 10,11=10,20;20,21=21
4

---

[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:10018][N-:10005][H:10019].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('5\tsp3\tNone\t2', '10005\tsigma\t10018\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-].[NH2-:10]>>[H:20][NH2:10].CC[C@@-:21](C)[N+](=O)[O-].[NH2-] 10=20;20,21=21
n_N > σ^*_N-H [H:21][NH-:20].CC[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H-:21].CC[C@@H](C)[N+](=O)[O-].[NH2:10][NH-:20] 10=20;20,21=21
5

---

[H:10015][C:10006]([H:10016])([H:10017])[C:10002]([H:10013])([H:10014])[C@@:10003]([H:10004])([C:10001]([H:10010])([H:10011])[H:10012])[N+:10007](=[O:10008])[O-:10009].[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10003\tsigma\t10002\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)[N+](=O)[O-].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-C > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].C[CH2:11][C@@H:10](C)[N+](=O)[O-].[NH2-]>>[H][C@@:10]([H:20])(C)[N+](=O)[O-].C[CH2+:11].CC[C@@-:21](C)[N+](=O)[O-].[NH2-] 10,11=10,20;20,21=21
6

---

[H:10015][C:10006]([H:10016])([H:10017])[C:10002]([H:10013])([H:10014])[C@@:10003]([H:10004])([C:10001]([H:10010])([H:10011])[H:10012])[N+:10007](=[O:10008])[O-:10009].[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10008\tpi\t10007\t2; 10003\tsigma\t10002\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)[N+](=O)[O-].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-C > π_O=N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].C[CH2:13][C@@H:12](C)[N+:11](=[O:10])[O-].[NH2-]>>[H:20][O:10][N+:11](=[C@@H:12]C)[O-].C[CH2+:13].CC[C@@-:21](C)[N+](=O)[O-].[NH2-] 10,11=10,20;12,13=11,12;20,21=21
6

---

[H:10015][C:10006]([H:10016])([H:10017])[C:10002]([H:10013])([H:10014])[C@@:10003]([H:10004])([C:10001]([H:10010])([H:10011])[H:10012])[N+:10007](=[O:10008])[O-:10009].[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10003\tsigma\t10004\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)[N+](=O)[O-].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-H > σ^*_H-C [H:11][C@@:10](C)(CC)[N+](=O)[O-].[H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-]>>[H+:11].[H:20][C@@:10](C)(CC)[N+](=O)[O-].CC[C@@-:21](C)[N+](=O)[O-].[NH2-] 10,11=10,20;20,21=21
6

---

[H:10015][C:10006]([H:10016])([H:10017])[C:10002]([H:10013])([H:10014])[C@@:10003]([H:10004])([C:10001]([H:10010])([H:10011])[H:10012])[N+:10007](=[O:10008])[O-:10009].[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10008\tpi\t10007\t2; 10003\tsigma\t10004\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)[N+](=O)[O-].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-H > π_O=N > σ^*_H-C [H:13][C@@:12](C)(CC)[N+:11](=[O:10])[O-].[H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-]>>[H+:13].[H:20][O:10][N+:11](=[C@:12](C)CC)[O-].CC[C@@-:21](C)[N+](=O)[O-].[NH2-] 10,11=10,20;12,13=11,12;20,21=21
6

---

[H:10015][C:10006]([H:10016])([H:10017])[C:10002]([H:10013])([H:10014])[C@@:10003]([H:10004])([C:10001]([H:10010])([H:10011])[H:10012])[N+:10007](=[O:10008])[O-:10009].[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10003\tsigma\t10001\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)[N+](=O)[O-].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-C > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H:10]([CH3:11])[N+](=O)[O-].[NH2-]>>[H][C@@:10]([H:20])(CC)[N+](=O)[O-].[CH3+:11].CC[C@@-:21](C)[N+](=O)[O-].[NH2-] 10,11=10,20;20,21=21
6

---

[H:10015][C:10006]([H:10016])([H:10017])[C:10002]([H:10013])([H:10014])[C@@:10003]([H:10004])([C:10001]([H:10010])([H:10011])[H:10012])[N+:10007](=[O:10008])[O-:10009].[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10008\tpi\t10007\t2; 10003\tsigma\t10001\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)[N+](=O)[O-].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-C > π_O=N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H:12]([CH3:13])[N+:11](=[O:10])[O-].[NH2-]>>[H:20][O:10][N+:11](=[C@@H:12]CC)[O-].[CH3+:13].CC[C@@-:21](C)[N+](=O)[O-].[NH2-] 10,11=10,20;12,13=11,12;20,21=21
6

---

[H:10015][C:10006]([H:10016])([H:10017])[C:10002]([H:10013])([H:10014])[C@@:10003]([H:10004])([C:10001]([H:10010])([H:10011])[H:10012])[N+:10007](=[O:10008])[O-:10009].[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10003\tsigma\t10007\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)[N+](=O)[O-].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_C-N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H:10](C)[N+:11](=O)[O-].[NH2-]>>[H][C@:10]([H:20])(C)CC.CC[C@@-:21](C)[N+](=O)[O-].[NH2-].[N+2:11](=O)[O-] 10,11=10,20;20,21=21
6

---

[H:10015][C:10006]([H:10016])([H:10017])[C:10002]([H:10013])([H:10014])[C@@:10003]([H:10004])([C:10001]([H:10010])([H:10011])[H:10012])[N+:10007](=[O:10008])[O-:10009].[H:15][C:6]([H:16])([H:17])[C:2]([H:13])([H:14])[C@@:3]([H:4])([C:1]([H:10])([H:11])[H:12])[N+:7](=[O:8])[O-:9].[H:18][N-:5][H:19]
('5\tsp3\tNone\t2', '4\tsigma\t3\t2') ('10004\tsigma\t10003\t2', '4\tsigma\t3\t2')
n_N > σ^*_H-C [H:20][C@@:21](C)(CC)[N+](=O)[O-].CC[C@@H](C)[N+](=O)[O-].[NH2-:10]>>[H:20][NH2:10].CC[C@@H](C)[N+](=O)[O-].CC[C@@-:21](C)[N+](=O)[O-] 10=20;20,21=21
σ_H-C > σ^*_H-C [H:10][C@@:11](C)(CC)[N+](=O)[O-].[H:20][C@@:21](C)(CC)[N+](=O)[O-].[NH2-]>>[H:10][H:20].CC[C@@-:21](C)[N+](=O)[O-].CC[C@@+:11](C)[N+](=O)[O-].[NH2-] 10,11=10,20;20,21=21
6

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '3\tsigma\t6\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-C [CH:20]1=CC(=NC=[CH:21]1)Cl.[NH2-:10]>>[CH-:21]=CN=C(C=[CH:20][NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '9\tsigma\t4\t2; 3\tsigma\t6\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][C:21]1=[CH:22][CH:23]=CN=C1Cl.[NH2-:10]>>[H:20][NH2:10].[CH-:23]=CN=C([C:21]#[CH:22])Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '3\tpi\t4\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C [CH:20]1=[CH:21]C(=NC=C1)Cl.[NH2-:10]>>[CH-:21]1[CH:20](C=CN=C1Cl)[NH2:10] 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '5\tpi\t6\t2; 3\tpi\t4\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C > π^*_C=C [CH:22]1=[CH:23]C(=N[CH:20]=[CH:21]1)Cl.[NH2-:10]>>[CH-:23]1[CH:22]=[CH:21][CH:20](N=C1Cl)[NH2:10] 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '12\tsigma\t6\t2; 3\tpi\t4\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > π^*_C=C [H:20][C:21]1=CN=C([CH:23]=[CH:22]1)Cl.[NH2-:10]>>[H:20][NH2:10].[CH-:23]1[CH:22]=[C:21]=CN=C1Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '3\tsigma\t8\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-H [H:21][C:20]1=CC(=NC=C1)Cl.[NH2-:10]>>[H-:21].C1=CN=C(C=[C:20]1[NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '5\tpi\t6\t2; 3\tsigma\t8\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C > σ^*_C-H [H:23][C:22]1=CC(=N[CH:20]=[CH:21]1)Cl.[NH2-:10]>>[H-:23].[CH:21]1=[C:22]=CC(=N[CH:20]1[NH2:10])Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '12\tsigma\t6\t2; 3\tsigma\t8\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:23][C:22]1=CC(=NC=[C:21]1[H:20])Cl.[NH2-:10]>>[H-:23].[H:20][NH2:10].C1=[C:22]=[C:21]=CN=C1Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '9\tsigma\t4\t2; 3\tsigma\t8\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:23][C:22]1=[C:21](C(=NC=C1)Cl)[H:20].[NH2-:10]>>[H-:23].[H:20][NH2:10].C1=CN=C([C:21]#[C:22]1)Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '4\tpi\t3\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C [CH:21]1=[CH:20]C(=NC=C1)Cl.[NH2-:10]>>[CH-:21]1C=CN=C([CH:20]1[NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '2\tpi\t1\t2; 4\tpi\t3\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_N=C > π^*_C=C [CH:23]1=[CH:22][C:21](=[N:20]C=C1)Cl.[NH2-:10]>>[CH-:23]1C=C[N:20]([C:21](=[CH:22]1)Cl)[NH2:10] 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '4\tsigma\t1\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-C C1=[CH:20][C:21](=NC=C1)Cl.[NH2-:10]>>C(=[CH:20][NH2:10])C=CN=[C-:21]Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '8\tsigma\t3\t2; 4\tsigma\t1\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][C:21]1=[CH:22][C:23](=NC=C1)Cl.[NH2-:10]>>[H:20][NH2:10].[CH:22]#[C:21]C=CN=[C-:23]Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '4\tsigma\t9\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-H [H:21][C:20]1=CC=CN=C1Cl.[NH2-:10]>>[H-:21].C1=CN=C([C:20](=C1)[NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '2\tpi\t1\t2; 4\tsigma\t9\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_N=C > σ^*_C-H [H:23][C:22]1=CC=C[N:20]=[C:21]1Cl.[NH2-:10]>>[H-:23].C1=C[N:20]([C:21](=[C:22]=C1)Cl)[NH2:10] 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '1\tsigma\t4\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-C C1=[CH:21][C:20](=NC=C1)Cl.[NH2-:10]>>[CH-:21]=CC=CN=[C:20]([NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '3\tpi\t4\t2; 1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C > π^*_C=N [CH:20]1=[CH:21][C:22](=[N:23]C=C1)Cl.[NH2-:10]>>C1=C[N-:23][C:22](=[CH:21][CH:20]1[NH2:10])Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '9\tsigma\t4\t2; 1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > π^*_C=N [H:20][C:21]1=CC=C[N:23]=[C:22]1Cl.[NH2-:10]>>[H:20][NH2:10].C1=C[N-:23][C:22](=[C:21]=C1)Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '1\tsigma\t7\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-Cl C1=C[C:20](=NC=C1)[Cl:21].[NH2-:10]>>C1=C[C:20](=NC=C1)[NH2:10].[Cl-:21] 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '3\tpi\t4\t2; 1\tsigma\t7\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C > σ^*_C-Cl [CH:20]1=[CH:21][C:22](=NC=C1)[Cl:23].[NH2-:10]>>C1=CN=[C:22]=[CH:21][CH:20]1[NH2:10].[Cl-:23] 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '9\tsigma\t4\t2; 1\tsigma\t7\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-Cl [H:20][C:21]1=CC=CN=[C:22]1[Cl:23].[NH2-:10]>>[H:20][NH2:10].C1=CN=[C:22]=[C:21]=C1.[Cl-:23] 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '2\tpi\t1\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_N=C C1=C[C:21](=[N:20]C=C1)Cl.[NH2-:10]>>C1=C[C-:21]([N:20](C=C1)[NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '6\tpi\t5\t2; 2\tpi\t1\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C > π^*_N=C C1=C[C:23](=[N:22][CH:21]=[CH:20]1)Cl.[NH2-:10]>>C1=C[C-:23]([N:22]=[CH:21][CH:20]1[NH2:10])Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '11\tsigma\t5\t2; 2\tpi\t1\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > π^*_N=C [H:20][C:21]1=CC=C[C:23](=[N:22]1)Cl.[NH2-:10]>>[H:20][NH2:10].C1=C[C-:23]([N:22]=[C:21]=C1)Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '2\tsigma\t5\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_N-C C1=CC(=[N:20][CH:21]=C1)Cl.[NH2-:10]>>[CH-:21]=CC=CC(=[N:20][NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '5\tsigma\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-N C1=CC(=[N:21][CH:20]=C1)Cl.[NH2-:10]>>C(=CC(=[N-:21])Cl)C=[CH:20][NH2:10] 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '12\tsigma\t6\t2; 5\tsigma\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-N [H:20][C:21]1=[CH:22][N:23]=C(C=C1)Cl.[NH2-:10]>>[H:20][NH2:10].[CH:22]#[C:21]C=CC(=[N-:23])Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '5\tpi\t6\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C C1=CC(=N[CH:20]=[CH:21]1)Cl.[NH2-:10]>>[CH-:21]1C=CC(=N[CH:20]1[NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '1\tpi\t2\t2; 5\tpi\t6\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=N > π^*_C=C C1=C[C:20](=[N:21][CH:22]=[CH:23]1)Cl.[NH2-:10]>>[CH-:23]1C=C[C:20]([N:21]=[CH:22]1)([NH2:10])Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '5\tsigma\t11\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-H [H:21][C:20]1=CC=CC(=N1)Cl.[NH2-:10]>>[H-:21].C1=CC(=N[C:20](=C1)[NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '1\tpi\t2\t2; 5\tsigma\t11\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=N > σ^*_C-H [H:23][C:22]1=CC=C[C:20](=[N:21]1)Cl.[NH2-:10]>>[H-:23].C1=C[C:20]([N:21]=[C:22]=C1)([NH2:10])Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '12\tsigma\t6\t2; 5\tsigma\t11\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:20][C:21]1=[C:22](N=C(C=C1)Cl)[H:23].[NH2-:10]>>[H-:23].[H:20][NH2:10].C1=CC(=N[C:22]#[C:21]1)Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '6\tpi\t5\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C C1=CC(=N[CH:21]=[CH:20]1)Cl.[NH2-:10]>>[CH-:21]1[CH:20](C=CC(=N1)Cl)[NH2:10] 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '4\tpi\t3\t2; 6\tpi\t5\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C > π^*_C=C [CH:21]1=[CH:20]C(=N[CH:23]=[CH:22]1)Cl.[NH2-:10]>>[CH-:23]1[CH:22]=[CH:21][CH:20](C(=N1)Cl)[NH2:10] 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '8\tsigma\t3\t2; 6\tpi\t5\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > π^*_C=C [H:20][C:21]1=CC(=N[CH:23]=[CH:22]1)Cl.[NH2-:10]>>[H:20][NH2:10].[CH-:23]1[CH:22]=[C:21]=CC(=N1)Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '6\tsigma\t3\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-C [CH:21]1=CC(=NC=[CH:20]1)Cl.[NH2-:10]>>[CH-:21]=CC(=NC=[CH:20][NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '11\tsigma\t5\t2; 6\tsigma\t3\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][C:21]1=[CH:22][CH:23]=CC(=N1)Cl.[NH2-:10]>>[H:20][NH2:10].[CH-:23]=CC(=N[C:21]#[CH:22])Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '6\tsigma\t12\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_C-H [H:21][C:20]1=CN=C(C=C1)Cl.[NH2-:10]>>[H-:21].C1=CC(=NC=[C:20]1[NH2:10])Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '4\tpi\t3\t2; 6\tsigma\t12\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=C > σ^*_C-H [H:23][C:22]1=CN=C([CH:20]=[CH:21]1)Cl.[NH2-:10]>>[H-:23].[CH:21]1=[C:22]=CN=C([CH:20]1[NH2:10])Cl 10=20;20,21=21,22;22,23=23
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '7\tsigma\t1\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_Cl-C C1=C[C:21](=NC=C1)[Cl:20].[NH2-:10]>>C1=C[C-:21]=NC=C1.[NH2:10][Cl:20] 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '8\tsigma\t3\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C [H:20][C:21]1=CC(=NC=C1)Cl.[NH2-:10]>>[H:20][NH2:10].C1=CN=C(C=[C-:21]1)Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '9\tsigma\t4\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C [H:20][C:21]1=CC=CN=C1Cl.[NH2-:10]>>[H:20][NH2:10].C1=CN=C([C-:21]=C1)Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '11\tsigma\t5\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C [H:20][C:21]1=CC=CC(=N1)Cl.[NH2-:10]>>[H:20][NH2:10].C1=CC(=N[C-:21]=C1)Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '12\tsigma\t6\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > σ^*_H-C [H:20][C:21]1=CN=C(C=C1)Cl.[NH2-:10]>>[H:20][NH2:10].C1=CC(=NC=[C-:21]1)Cl 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('3\tsigma\t6\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-C > π^*_C=N [CH:10]1=C[C:20](=[N:21]C=[CH:11]1)Cl.[NH2-]>>[CH+:11]=C[N-:21][C:20]1(C=[CH:10]1)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('3\tpi\t4\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_C=C > π^*_C=N [CH:10]1=[CH:11][C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=C[N-:21][C:20]2([CH:10]1[CH+:11]2)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('5\tpi\t6\t2; 3\tpi\t4\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_C=C > π_C=C > π^*_C=N [CH:12]1=[CH:13][C:20](=[N:21][CH:10]=[CH:11]1)Cl.[NH2-]>>[CH:12]1=[CH:11][CH:10]2[C:20]([CH+:13]1)([N-:21]2)Cl.[NH2-] 10,11=10,20;12,13=11,12;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('3\tsigma\t8\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-H > π^*_C=N [H:11][C:10]1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>[H+:11].C1=C[N-:21][C:20]2([C:10]1=C2)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('5\tpi\t6\t2; 3\tsigma\t8\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-H > π_C=C > π^*_C=N [H:13][C:12]1=C[C:20](=[N:21][CH:10]=[CH:11]1)Cl.[NH2-]>>[H+:13].[CH:11]1=[C:12]=C[C:20]2([CH:10]1[N-:21]2)Cl.[NH2-] 10,11=10,20;12,13=11,12;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('4\tpi\t3\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_C=C > π^*_C=N [CH:11]1=[CH:10][C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=C[N-:21][C:20](=[CH:10][CH+:11]1)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('4\tsigma\t9\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-H > π^*_C=N [H:11][C:10]1=CC=C[N:21]=[C:20]1Cl.[NH2-]>>[H+:11].C1=C[N-:21][C:20](=[C:10]=C1)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('5\tpi\t6\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_C=C > π^*_C=N C1=C[C:20](=[N:21][CH:10]=[CH:11]1)Cl.[NH2-]>>C1=C[C:20]2([CH:10]([CH+:11]1)[N-:21]2)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('5\tsigma\t11\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-H > π^*_C=N [H:11][C:10]1=CC=C[C:20](=[N:21]1)Cl.[NH2-]>>[H+:11].C1=C[C:20]2([C:10](=C1)[N-:21]2)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('6\tpi\t5\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_C=C > π^*_C=N C1=C[C:20](=[N:21][CH:11]=[CH:10]1)Cl.[NH2-]>>C1=C[C:20]2([CH:10]1[CH+:11][N-:21]2)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('4\tpi\t3\t2; 6\tpi\t5\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_C=C > π_C=C > π^*_C=N [CH:11]1=[CH:10][C:20](=[N:21][CH:13]=[CH:12]1)Cl.[NH2-]>>[CH:11]1=[CH:12][CH+:13][N-:21][C:20](=[CH:10]1)Cl.[NH2-] 10,11=10,20;12,13=11,12;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('6\tsigma\t3\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-C > π^*_C=N [CH:11]1=C[C:20](=[N:21]C=[CH:10]1)Cl.[NH2-]>>[CH+:11]=C[C:20]1([CH:10]=C[N-:21]1)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('6\tsigma\t12\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-H > π^*_C=N [H:11][C:10]1=C[N:21]=[C:20](C=C1)Cl.[NH2-]>>[H+:11].C1=C[C:20]2([C:10]1=C[N-:21]2)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('4\tpi\t3\t2; 6\tsigma\t12\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-H > π_C=C > π^*_C=N [H:13][C:12]1=C[N:21]=[C:20]([CH:10]=[CH:11]1)Cl.[NH2-]>>[H+:13].[CH:11]1=[C:12]=C[N-:21][C:20](=[CH:10]1)Cl.[NH2-] 10,11=10,20;12,13=11,12;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('7\tsp3\tNone\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_Cl > π^*_C=N C1=C[C:20](=[N:21]C=C1)[Cl:10].[NH2-]>>C1=C[C:20](=[Cl+:10])[N-:21]C=C1.[NH2-] 10=20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsigma\t13\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_N-H > π^*_C=N [H:11][NH-:10].C1=C[C:20](=[N:21]C=C1)Cl>>[H+:11].C1=C[C:20]([N-:21]C=C1)([NH-:10])Cl 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('8\tsigma\t3\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_H-C > π^*_C=N [H:10][C:11]1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>[H:10][C:20]1(C=[C+:11]C=C[N-:21]1)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('9\tsigma\t4\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_H-C > π^*_C=N [H:10][C:11]1=CC=C[N:21]=[C:20]1Cl.[NH2-]>>[H:10][C:20]1([C+:11]=CC=C[N-:21]1)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('11\tsigma\t5\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_H-C > π^*_C=N [H:10][C:11]1=CC=C[C:20](=[N:21]1)Cl.[NH2-]>>[H:10][C:20]1(C=CC=[C+:11][N-:21]1)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('12\tsigma\t6\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_H-C > π^*_C=N [H:10][C:11]1=C[N:21]=[C:20](C=C1)Cl.[NH2-]>>[H:10][C:20]1(C=C[C+:11]=C[N-:21]1)Cl.[NH2-] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('13\tsigma\t10\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_H-N > π^*_C=N [H:10][NH-:11].C1=C[C:20](=[N:21]C=C1)Cl>>[H:10][C:20]1(C=CC=C[N-:21]1)Cl.[NH:11] 10,11=10,20;20,21=21
7

---

[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:10013][N-:10010][H:10014].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10\tsp3\tNone\t2', '10010\tsigma\t10013\t2')
n_N > π^*_C=N C1=C[C:20](=[N:21]C=C1)Cl.[NH2-].[NH2-:10]>>C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl.[NH2-] 10=20;20,21=21
n_N > σ^*_N-H [H:21][NH-:20].C1=CC(=NC=C1)Cl.[NH2-:10]>>[H-:21].C1=CC(=NC=C1)Cl.[NH2:10][NH-:20] 10=20;20,21=21
8

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10001\tsigma\t10004\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-C > π^*_C=N C1=[CH:11][C:10](=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>[CH+:11]=CC=CN=[C:10]([C:20]1(C=CC=C[N-:21]1)Cl)Cl.[NH2-] 10,11=10,20;20,21=21
9

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10001\tpi\t10002\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_C=N > π^*_C=N C1=C[C:10](=[N:11]C=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=C[C:20]([N-:21]C=C1)([C:10]2(C=CC=C[N+:11]2)Cl)Cl.[NH2-] 10,11=10,20;20,21=21
9

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10003\tpi\t10004\t2; 10001\tpi\t10002\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_C=N > π_C=C > π^*_C=N [CH:10]1=[CH:11][C:12](=[N:13]C=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=C[C:20]([N-:21]C=C1)([CH:10]2C=C[N+:13][C:12](=[CH:11]2)Cl)Cl.[NH2-] 10,11=10,20;12,13=11,12;20,21=21
9

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10001\tsigma\t10007\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-Cl > π^*_C=N C1=C[C:10](=NC=C1)[Cl:11].C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=C[C:10](=NC=C1)[C:20]2(C=CC=C[N-:21]2)Cl.[NH2-].[Cl+:11] 10,11=10,20;20,21=21
9

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10003\tpi\t10004\t2; 10001\tsigma\t10007\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_C-Cl > π_C=C > π^*_C=N [CH:10]1=[CH:11][C:12](=NC=C1)[Cl:13].C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=C[C:20]([N-:21]C=C1)([CH:10]2C=CN=[C:12]=[CH:11]2)Cl.[NH2-].[Cl+:13] 10,11=10,20;12,13=11,12;20,21=21
9

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10002\tpi\t10001\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_N=C > π^*_C=N C1=C[C:11](=[N:10]C=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=C[C+:11]([N:10](C=C1)[C:20]2(C=CC=C[N-:21]2)Cl)Cl.[NH2-] 10,11=10,20;20,21=21
9

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10006\tpi\t10005\t2; 10002\tpi\t10001\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
π_N=C > π_C=C > π^*_C=N C1=C[C:13](=[N:12][CH:11]=[CH:10]1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=C[C:20]([N-:21]C=C1)([CH:10]2C=C[C+:13]([N:12]=[CH:11]2)Cl)Cl.[NH2-] 10,11=10,20;12,13=11,12;20,21=21
9

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10002\tsigma\t10005\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
σ_N-C > π^*_C=N C1=CC(=[N:10][CH:11]=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>[CH+:11]=CC=CC(=[N:10][C:20]1(C=CC=C[N-:21]1)Cl)Cl.[NH2-] 10,11=10,20;20,21=21
9

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10002\tsp2\tNone\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π^*_C=N C1=CC(=[N:10]C=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=CC(=[N+:10](C=C1)[C:20]2(C=CC=C[N-:21]2)Cl)Cl.[NH2-] 10=20;20,21=21
9

---

[H:10008][C:10003]1=[C:10004]([C:10001](=[N:10002][C:10005](=[C:10006]1[H:10012])[H:10011])[Cl:10007])[H:10009].[H:8][C:3]1=[C:4]([C:1](=[N:2][C:5](=[C:6]1[H:12])[H:11])[Cl:7])[H:9].[H:13][N-:10][H:14]
('10\tsp3\tNone\t2', '1\tpi\t2\t2') ('10006\tpi\t10005\t2; 10002\tsp2\tNone\t2', '1\tpi\t2\t2')
n_N > π^*_C=N C1=CC(=NC=C1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-:10]>>C1=CC(=NC=C1)Cl.C1=C[C:20]([N-:21]C=C1)([NH2:10])Cl 10=20;20,21=21
n_N > π_C=C > π^*_C=N C1=CC(=[N:12][CH:11]=[CH:10]1)Cl.C1=C[C:20](=[N:21]C=C1)Cl.[NH2-]>>C1=C[C:20]([N-:21]C=C1)([CH:10]2C=CC(=[N+:12]=[CH:11]2)Cl)Cl.[NH2-] 10,11=10,20;12=11;20,21=21
9

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '3\tsigma\t6\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-C [CH:20]1=C[C@]([N-:10]C=[CH:21]1)(N)Cl>>[CH-:21]=C[N:10]1[CH:20]=C[C@]1(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '9\tsigma\t4\t2; 3\tsigma\t6\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][C:21]1=[CH:22][CH:23]=C[N-:10][C@@]1(N)Cl>>[H:20][N:10](C=[CH-:23])[C@@]([C:21]#[CH:22])(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '3\tpi\t4\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C [CH:20]1=[CH:21][C@]([N-:10]C=C1)(N)Cl>>[CH-:21]1[CH:20]2C=C[N:10]2[C@@]1(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '5\tpi\t6\t2; 3\tpi\t4\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C > π^*_C=C [CH:22]1=[CH:23][C@]([N-:10][CH:20]=[CH:21]1)(N)Cl>>[CH-:23]1[CH:22]=[CH:21][CH:20]=[N:10][C@@]1(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '12\tsigma\t6\t2; 3\tpi\t4\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > π^*_C=C [H:20][C:21]1=C[N-:10][C@@]([CH:23]=[CH:22]1)(N)Cl>>[H:20][N:10]1C=[C:21]=[CH:22][CH-:23][C@]1(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '3\tsigma\t8\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-H [H:21][C:20]1=C[C@]([N-:10]C=C1)(N)Cl>>[H-:21].C1=C[N:10]2[C:20]1=C[C@]2(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '5\tpi\t6\t2; 3\tsigma\t8\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C > σ^*_C-H [H:23][C:22]1=C[C@]([N-:10][CH:20]=[CH:21]1)(N)Cl>>[H-:23].[CH:21]1=[C:22]=C[C@]([N:10]=[CH:20]1)(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '12\tsigma\t6\t2; 3\tsigma\t8\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:23][C:22]1=C[C@]([N-:10]C=[C:21]1[H:20])(N)Cl>>[H-:23].[H:20][N:10]1C=[C:21]=[C:22]=C[C@]1(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '9\tsigma\t4\t2; 3\tsigma\t8\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:23][C:22]1=[C:21]([C@]([N-:10]C=C1)(N)Cl)[H:20]>>[H-:23].[H:20][N:10]1C=C[C:22]#[C:21][C@]1(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '4\tpi\t3\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C [CH:21]1=[CH:20][C@]([N-:10]C=C1)(N)Cl>>[CH-:21]1C=C[N:10]2[CH:20]1[C@]2(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '4\tsigma\t1\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-C C1=[CH:20][C@:21]([N-:10]C=C1)(N)Cl>>C1=[CH:20][N:10](C=C1)[C@-:21](N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '8\tsigma\t3\t2; 4\tsigma\t1\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][C:21]1=[CH:22][C@:23]([N-:10]C=C1)(N)Cl>>[H:20][N:10](C=C[C:21]#[CH:22])[C@-:23](N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '4\tsigma\t9\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-H [H:21][C:20]1=CC=C[N-:10][C@@]1(N)Cl>>[H-:21].C1=C[N:10]2[C:20](=C1)[C@]2(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '1\tsigma\t4\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-C C1=[CH:21][C@:20]([N-:10]C=C1)(N)Cl>>[CH-:21]=CC=C[N:10]=[C@:20](N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '13\tsigma\t7\t2; 1\tsigma\t4\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-N > σ^*_C-C [H:20][NH:21][C@@:22]1([CH:23]=CC=C[N-:10]1)Cl>>[H:20][N:10](C=CC=[CH-:23])[C@:22](=[NH:21])Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '1\tsigma\t7\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-N C1=C[C@:20]([N-:10]C=C1)([NH2:21])Cl>>C1=C[C@:20](=[N:10]C=C1)Cl.[NH2-:21] 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '3\tpi\t4\t2; 1\tsigma\t7\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C > σ^*_C-N [CH:20]1=[CH:21][C@:22]([N-:10]C=C1)([NH2:23])Cl>>C1=C[N:10]2[CH:20]1[CH:21]=[C@:22]2Cl.[NH2-:23] 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '9\tsigma\t4\t2; 1\tsigma\t7\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-N [H:20][C:21]1=CC=C[N-:10][C@@:22]1([NH2:23])Cl>>[H:20][N:10]1C=CC=[C:21]=[C@:22]1Cl.[NH2-:23] 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '3\tpi\t4\t2; 1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C > σ^*_C-Cl [CH:20]1=[CH:21][C@:22]([N-:10]C=C1)(N)[Cl:23]>>C1=C[N:10]2[CH:20]1[CH:21]=[C@@:22]2N.[Cl-:23] 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '9\tsigma\t4\t2; 1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-Cl [H:20][C:21]1=CC=C[N-:10][C@@:22]1(N)[Cl:23]>>[H:20][N:10]1C=CC=[C:21]=[C@@:22]1N.[Cl-:23] 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '13\tsigma\t7\t2; 1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-N > σ^*_C-Cl [H:20][NH:21][C@@:22]1(C=CC=C[N-:10]1)[Cl:23]>>[H:20][N:10]1C=CC=C[C@@:22]1=[NH:21].[Cl-:23] 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '5\tpi\t6\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C C1=C[C@]([N-:10][CH:20]=[CH:21]1)(N)Cl>>[CH-:21]1C=C[C@]([N:10]=[CH:20]1)(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '5\tsigma\t11\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-H [H:21][C:20]1=CC=C[C@]([N-:10]1)(N)Cl>>[H-:21].C1=C[C@]([N:10]=[C:20]=C1)(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '12\tsigma\t6\t2; 5\tsigma\t11\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-H [H:20][C:21]1=[C:22]([N-:10][C@@](C=C1)(N)Cl)[H:23]>>[H-:23].[H:20][N:10]1[C:22]#[C:21]C=C[C@]1(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '6\tpi\t5\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C C1=C[C@]([N-:10][CH:21]=[CH:20]1)(N)Cl>>[CH-:21]1[CH:20]2[N:10]1[C@@](C=C2)(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '4\tpi\t3\t2; 6\tpi\t5\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C > π^*_C=C [CH:21]1=[CH:20][C@]([N-:10][CH:23]=[CH:22]1)(N)Cl>>[CH-:23]1[CH:22]=[CH:21][CH:20]2[N:10]1[C@@]2(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '8\tsigma\t3\t2; 6\tpi\t5\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > π^*_C=C [H:20][C:21]1=C[C@]([N-:10][CH:23]=[CH:22]1)(N)Cl>>[H:20][N:10]1[CH-:23][CH:22]=[C:21]=C[C@]1(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '6\tsigma\t3\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-C [CH:21]1=C[C@]([N-:10]C=[CH:20]1)(N)Cl>>[CH-:21]=C[C@@](N)([N:10]1C=[CH:20]1)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '11\tsigma\t5\t2; 6\tsigma\t3\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C > σ^*_C-C [H:20][C:21]1=[CH:22][CH:23]=C[C@]([N-:10]1)(N)Cl>>[H:20][N:10]([C:21]#[CH:22])[C@@](C=[CH-:23])(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '6\tsigma\t12\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-H [H:21][C:20]1=C[N-:10][C@@](C=C1)(N)Cl>>[H-:21].C1=C[C@]([N:10]2[C:20]1=C2)(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '4\tpi\t3\t2; 6\tsigma\t12\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π^*_C=C > σ^*_C-H [H:23][C:22]1=C[N-:10][C@@]([CH:20]=[CH:21]1)(N)Cl>>[H-:23].[CH:21]1=[C:22]=C[N:10]2[CH:20]1[C@]2(N)Cl 10=20;20,21=21,22;22,23=23
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '7\tsigma\t1\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_N-C C1=C[C@:21]([N-:10]C=C1)([NH2:20])Cl>>C1=C[C@-:21]([N:10](C=C1)[NH2:20])Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '7\tsigma\t13\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_N-H [H:21][NH:20][C@@]1(C=CC=C[N-:10]1)Cl>>[H-:21].C1=C[C@]2([NH:20][N:10]2C=C1)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '10\tsigma\t1\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_Cl-C C1=C[C@:21]([N-:10]C=C1)(N)[Cl:20]>>C1=C[C@-:21]([N:10](C=C1)[Cl:20])N 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '8\tsigma\t3\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C [H:20][C:21]1=C[C@]([N-:10]C=C1)(N)Cl>>[H:20][N:10]1C=C[C-:21]=C[C@]1(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '9\tsigma\t4\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C [H:20][C:21]1=CC=C[N-:10][C@@]1(N)Cl>>[H:20][N:10]1C=CC=[C-:21][C@]1(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '11\tsigma\t5\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C [H:20][C:21]1=CC=C[C@]([N-:10]1)(N)Cl>>[H:20][N:10]1[C-:21]=CC=C[C@]1(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '12\tsigma\t6\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-C [H:20][C:21]1=C[N-:10][C@@](C=C1)(N)Cl>>[H:20][N:10]1C=[C-:21]C=C[C@]1(N)Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsp3\tNone\t2', '13\tsigma\t7\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_H-N [H:20][NH:21][C@@]1(C=CC=C[N-:10]1)Cl>>[H:20][N:10]1C=CC=C[C@]1([NH-:21])Cl 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('3\tsigma\t6\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_C-C > σ^*_C-Cl [CH:10]1=C[C@:20]([N-]C=[CH:11]1)(N)[Cl:21]>>[CH+:11]=C[N-][C@:20]1(C=[CH:10]1)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('3\tpi\t4\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
π_C=C > σ^*_C-Cl [CH:10]1=[CH:11][C@:20]([N-]C=C1)(N)[Cl:21]>>C1=C[N-][C@@:20]2([CH:10]1[CH+:11]2)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('5\tpi\t6\t2; 3\tpi\t4\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
π_C=C > π_C=C > σ^*_C-Cl [CH:12]1=[CH:13][C@:20]([N-][CH:10]=[CH:11]1)(N)[Cl:21]>>[CH:12]1=[CH:11][CH:10]2[C@:20]([CH+:13]1)([N-]2)N.[Cl-:21] 10,11=10,20;12,13=11,12;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('3\tsigma\t8\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_C-H > σ^*_C-Cl [H:11][C:10]1=C[C@:20]([N-]C=C1)(N)[Cl:21]>>[H+:11].C1=C[N-][C@@:20]2([C:10]1=C2)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('5\tpi\t6\t2; 3\tsigma\t8\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_C-H > π_C=C > σ^*_C-Cl [H:13][C:12]1=C[C@:20]([N-][CH:10]=[CH:11]1)(N)[Cl:21]>>[H+:13].[CH:11]1=[C:12]=C[C@:20]2([CH:10]1[N-]2)N.[Cl-:21] 10,11=10,20;12,13=11,12;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('4\tpi\t3\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
π_C=C > σ^*_C-Cl [CH:11]1=[CH:10][C@:20]([N-]C=C1)(N)[Cl:21]>>C1=C[N-][C@:20](=[CH:10][CH+:11]1)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('4\tsigma\t9\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_C-H > σ^*_C-Cl [H:11][C:10]1=CC=C[N-][C@@:20]1(N)[Cl:21]>>[H+:11].C1=C[N-][C@:20](=[C:10]=C1)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('2\tsigma\t5\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_N-C > σ^*_C-Cl C1=C[C@:20]([N-:10][CH:11]=C1)(N)[Cl:21]>>[CH+:11]=CC=C[C@@:20](=[N-:10])N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('6\tpi\t5\t2; 2\tsp3\tNone\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > π_C=C > σ^*_C-Cl C1=C[C@:20]([N-:12][CH:11]=[CH:10]1)(N)[Cl:21]>>C1=C[C@:20]2([CH:10]1[CH:11]=[N:12]2)N.[Cl-:21] 10,11=10,20;12=11;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('5\tsigma\t2\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_C-N > σ^*_C-Cl C1=C[C@:20]([N-:11][CH:10]=C1)(N)[Cl:21]>>C1=C[C@:20]([CH:10]=C1)(N)[N:11].[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('5\tpi\t6\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
π_C=C > σ^*_C-Cl C1=C[C@:20]([N-][CH:10]=[CH:11]1)(N)[Cl:21]>>C1=C[C@:20]2([CH:10]([CH+:11]1)[N-]2)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('5\tsigma\t11\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_C-H > σ^*_C-Cl [H:11][C:10]1=CC=C[C@:20]([N-]1)(N)[Cl:21]>>[H+:11].C1=C[C@:20]2([C:10](=C1)[N-]2)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('6\tpi\t5\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
π_C=C > σ^*_C-Cl C1=C[C@:20]([N-][CH:11]=[CH:10]1)(N)[Cl:21]>>C1=C[C@:20]2([CH:10]1[CH+:11][N-]2)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('4\tpi\t3\t2; 6\tpi\t5\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
π_C=C > π_C=C > σ^*_C-Cl [CH:11]1=[CH:10][C@:20]([N-][CH:13]=[CH:12]1)(N)[Cl:21]>>[CH:11]1=[CH:12][CH+:13][N-][C@:20](=[CH:10]1)N.[Cl-:21] 10,11=10,20;12,13=11,12;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('6\tsigma\t3\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_C-C > σ^*_C-Cl [CH:11]1=C[C@:20]([N-]C=[CH:10]1)(N)[Cl:21]>>[CH+:11]=C[C@:20]1([CH:10]=C[N-]1)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('6\tsigma\t12\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_C-H > σ^*_C-Cl [H:11][C:10]1=C[N-][C@@:20](C=C1)(N)[Cl:21]>>[H+:11].C1=C[C@:20]2([C:10]1=C[N-]2)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('4\tpi\t3\t2; 6\tsigma\t12\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_C-H > π_C=C > σ^*_C-Cl [H:13][C:12]1=C[N-][C@@:20]([CH:10]=[CH:11]1)(N)[Cl:21]>>[H+:13].[CH:11]1=[C:12]=C[N-][C@:20](=[CH:10]1)N.[Cl-:21] 10,11=10,20;12,13=11,12;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('7\tsigma\t13\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_N-H > σ^*_C-Cl [H:11][NH:10][C@@:20]1(C=CC=C[N-]1)[Cl:21]>>[H+:11].C1=C[C@:20](=[NH:10])[N-]C=C1.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('7\tsp3\tNone\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
n_N > σ^*_C-Cl C1=C[C@:20]([N-]C=C1)([NH2:10])[Cl:21]>>C1=C[C@:20](=[NH2+:10])[N-]C=C1.[Cl-:21] 10=20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('8\tsigma\t3\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_H-C > σ^*_C-Cl [H:10][C:11]1=C[C@:20]([N-]C=C1)(N)[Cl:21]>>[H:10][C@@:20]1(C=[C+:11]C=C[N-]1)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('9\tsigma\t4\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_H-C > σ^*_C-Cl [H:10][C:11]1=CC=C[N-][C@@:20]1(N)[Cl:21]>>[H:10][C@@:20]1([C+:11]=CC=C[N-]1)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('11\tsigma\t5\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_H-C > σ^*_C-Cl [H:10][C:11]1=CC=C[C@:20]([N-]1)(N)[Cl:21]>>[H:10][C@@:20]1(C=CC=[C+:11][N-]1)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('12\tsigma\t6\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_H-C > σ^*_C-Cl [H:10][C:11]1=C[N-][C@@:20](C=C1)(N)[Cl:21]>>[H:10][C@@:20]1(C=C[C+:11]=C[N-]1)N.[Cl-:21] 10,11=10,20;20,21=21
10

---

[H:8][C:3]1=[C:4]([C@:1]([N-:2][C:5](=[C:6]1[H:12])[H:11])([N:7]([H:13])[H:14])[Cl:10])[H:9]
('2\tsp3\tNone\t2', '1\tsigma\t10\t2') ('13\tsigma\t7\t2', '1\tsigma\t10\t2')
n_N > σ^*_C-Cl C1=C[C@:20]([N-:10]C=C1)(N)[Cl:21]>>C1=C[C@@:20](=[N:10]C=C1)N.[Cl-:21] 10=20;20,21=21
σ_H-N > σ^*_C-Cl [H:10][NH:11][C@@:20]1(C=CC=C[N-]1)[Cl:21]>>[H:10][C@@:20]1(C=CC=C[N-]1)[NH+:11].[Cl-:21] 10,11=10,20;20,21=21
10

---